1,3,5-Triaryl 2-pyridylidene: base-promoted generation and complexation.
نویسندگان
چکیده
We herein report a base-promoted generation of sterically hindered 1,3,5-triaryl 2-pyridylidene from the corresponding pyridinium salt. The thus-generated 2-pyridylidene was trapped by S(8) and Me(2)SAuCl to form 2-pyridinethione and a 2-pyridylidene-gold(I) complex, respectively. Rearrangement of pyridylidene to pyrido[1,2-a]indole indicates high reactivity of the carbene center of 2-pyridylidene.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 53 شماره
صفحات -
تاریخ انتشار 2012